anhydrous ammonia sds

Section 8. Anhydrous ammonia is a highly effective fertilizer that helps farmers feed our growing population and replenish nutrients in the soil. • Ammonia can be used in … Component Analysis - Aquatic Toxicity AMMONIA, ANHYDROUS 7664 … Occupational Safety & Health Administration (OSHA): This material is considered to be hazardous as defined by the OSHA Hazard Communication Standard 29 CFR 1910.1200. Preparation Information: Revision Date November 1, 2018 Unauthorized use is strictly prohibited. Pulmonary edema may follow chemical bronchitis. Respiratory injury may appear as a delayed phenomenon. TLV: Threshold Limit Value Telephone (General): 215-322-1238 W�-�Н/�q�E�ݸ�R/��,�9�CW�@�b8��7.Z�cm< ��3�veb��z~��e�e+�f8>J�/Y:{I��FA�%�GA��Q�O� Bٯ�{��3�'�y�'�¯�r_��x>ڎ^C�)��! Dakota Gasification Company's anhydrous ammonia is a nitrogen fertilizer used on various types of agricultural crops. If conscious, give large amounts of water to drink. Synonym :ammonia; anhydrous ammonia SDS # :001003 Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Product Identifier and Company Identification Product name : Anhydrous Ammonia HBCC SDS number : CA10000 Synonym : Ammonia; NH 3 Product use and : Refer to label or call Restrictions Flammable Gases (Category 2) first aid instructions in Section 4 (First Aid Measures). 58 / Monday, March 26, 2012 / Rules and Regulations 12/13/2017 EN (English US) Page 1 SECTION 1: Identification 1.1. Refer to 49 CFR 172.302, General marking requirements for bulk packagings. endobj 6 0 obj <>stream The information contained here should not be confused with federal, state, municipal, or insurance requirements, or with national safety or building codes, and no representations or warranties are made with respect thereto. Water Spray, Water Fog, Dry Chemical, Carbon Dioxide (CO2) or foam. Refer to 49 CFR 172.301, General marking requirements for non-bulk packagings. As a fertilizer, it contains 82 percent nitrogen, the … Protective equipment should be stored near, but outside of anhydrous ammonia area. Page 3/9 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date: 04.02.2018 Revision: Version No: 6 04.02.2018 Trade name: Anhydrous Ammonia (Contd. : SDS-002-CLP Air Liquide UK Ltd. Station Road Coleshill B46 1JY Birmingham United Kingdom 01675 462424 EN (English) SDS Ref. In case of leaking gas fire: Stop flow of gas before extinguishing. In the United States, ammonia is primarily used as a feedstock to produce nitrogen fertilizers, such as urea an ammonium sulfate, and is also directly applied to soil as a fertilizer. Local exhaust should be sufficient to keep ammonia vapor below applicable exposure standards. Acute Toxicity, Corrosive, Gases Under Pressure, Flammable Gas, Acute Aquatic Toxicity, Classification: Note: (1 - Most Severe / 4 - Least Severe) P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Perform risk assessment prior to … OSHA 29 CFR 1910.111 prescribes handling and storage requirements for anhydrous ammonia. : 302 1/17 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA), Section 103, any environmental release of this chemical equal to or over the reportable quantity of 100 pounds must be reported promptly to the National Response Center, Washington, D.C. (1-800-424-8802). Anhydrous Ammonia - Refrigeration Grade Safety Data Sheet according to Federal Register / Vol. Because NH3 contains little or no water it aggressively seeks out moisture, be it from soil or your eyes, throat, lungs or skin. : SDS-002-CLP Air Liquide UK Ltd. Station Road, Coleshill B46 1JY Birmingham United Kingdom 01675462424 EN (English) SDS Ref. ?�C+��:$��Ps'��V�= ��$:�^�nA��ߠ[��]��"t ��h:�ߎj�(t-Z��S��d��>��E��e;a�Ch&|g�>�� _A��=Ȁ�4Õ��Q.��Ђ��zt��$�}6��Jn0��lK�\Ai4=��~�2�e볇��q#��O�%�+©�3�S(�*�p�O+�=n�2��3u0b�R9J��W� t��bA� Chronic toxicity to fish: NOEC = 0.025-1.2 mg un-ionized NH3/L. Call a doctor/physician and seek medical attention for severe exposure or if symptoms persist. Material Name: AMMONIA, ANHYDROUS SDS ID: MAT01050 _____ Page 9 of 12 Issue date: 2015-12-11 Revision 3.0 Print date: 2015-12-11 Section 12 - ECOLOGICAL INFORMATION Ecotoxicity Very toxic to aquatic life with long lasting effects. 77, No. Refer to 49 CFR 172.328, Cargo Tanks for additional marking requirements. A positive pressure SCBA is required for entry into ammonia atmospheres at or above 300 ppm (IDLH). Revisions by: HJS. first aid attention must be given as urgently as possible as outlined below. Precautionary Statement(s) Data Sheets. Biodegradable in soil. Irritation, corrosive burns, blister formation (vesiculation) may result. Stay upwind and use water spray downwind of container to absorb the evolved gas. IF ON SKIN: Immediately rinse skin and contaminated clothing with plenty of water before removing clothes. Section 1. Moreover, it should not be assumed that every acceptable test or safety procedure or method, precaution, equipment or device is contained within, or that abnormal or unusual circumstances may not warrant or suggest further requirements or additional procedures. Toxic Substances Control Act (TSCA): Listed in the TSCA Inventory. Pure ammonia (also known as anhydrous ammonia) is a pungent, colorless gas approximately 40% lighter than air. HAZARDOUS DECOMPOSITION PRODUCTS: HMIS Hazard Index: Leave the area of a spill by moving laterally and upwind. A positive pressure SCBA is required for entry into ammonia atmospheres at or above 300 ppm (IDLH). Ammonia, anhydrous Ammonia, 82-00-0, NH. Listed as hazardous substance under the Clean Water Act (CWA) (40 CFR 116.4 and 40 CFR 117.3). Very toxic to aquatic life. The manufacturing process is performed in a closed system combining high purity deionized water with anhydrous ammonia to produce a high quality aqua ammonia suitable for numerous applications. NFPA: National Fire Protection Association Store in a well-ventilated place. Select Country. Tearing, eye burns, permanent eye damage or blindness may occur. (OSHA) revised Hazard Communication Standard (HCS). select. all suspected anhydrous ammonia burns should receive medical Wash contaminated clothing before reuse. Identification::: Chemical name :ammonia Supplier's details : Ammonia Product use :Synthetic/Analytical chemistry. determine the appropriate hazard classification and personnel protective equipment (PPE) code for this material. Contains gas under pressure; may explode if heated. All rights reserved. HMIS® ratings are to be used with a fully implemented HMIS® program. �pS�=�A}�$h��˯�?�-�{��a\�~��C��'�r��B�a��x/Q��i�%��X�9��E��q�k�BOu�߆?�!��t�s��3��"t7z �� _��x�?��$��L$��2��ͮE�VC�DO@��#�c�C_`��$|3|n�w��6�n��_�o��,A�I��H|�d)��. Anhydrous Ammonia is a liquid when compressed and liquefied under high pressure and low temperature. Disclaimer: It is used in the production of fertilizers, explosives and polymers. NO open flames, NO sparks and NO smoking. Chemical name :ammonia, anhydrous Supplier's details : Ammonia Product use :Synthetic/Analytical chemistry. Classified as Resource Conservation and Recovery Act (RCRA) Hazardous Waste due to corrosivity with designation D002, if disposed of in original form. For first aid purposes, at least 5 gallons of clean water in a container designed to provide ready Exposure Controls / Personal Protection. Stay upwind when containers are threatened. Synonyms: Ammonia VENTILATION: Local exhaust should be sufficient to keep ammonia vapor below applicable exposure standards. SYNONYMS: Ammonia IF ON SKIN: Rinse immediately with plenty of water before removing clothes. Anhydrous Ammonia, 82-0-0 Safety Data Sheet according to Federal Register / Vol. Anhydrous ammonia SDS Ref. Mobility in Soil: The vapor is lighter than air with an extremely pungent odor. : 01-2119488876-14 Chemical formula : NH3. Section 8: Reformatted and added information for Canada and Mexico, Section 14.1: Updated information for Package Markings and added "Additional Information. Stop source of leak if possible, provided it can be done in a safe manner. CGA G2.1 - 2014 11.5.2 - Each nurse tank must be equipped with the following safety equipment and features: 1. Anhydrous ammonia SDS Ref. Store locked up. Soluble in water. NIOSH: National Institute for Occupational Safety and Health RESPIRATORY PROTECTION: Respiratory protection approved by NIOSH for ammonia must be used when applicable safety and health exposure limits are exceeded. Precautionary Statements: Not available Use in accordance with supplier’s recommendations CALAMCO POSSIBILITY OF HAZARDOUS REACTIONS: United Nations Model Regulations, Environmentally Hazardous: Yes. Stable under normal ambient conditions of temperature and pressure. Any party handling, transferring, transporting, storing, applying or otherwise using this product should review thoroughly all applicable laws, rules, regulations, standards and good engineering practices. DISPOSAL: Ammonia, anhydrous SDS US 915588 Version #: 01 Revision date: - Issue date: 26-February-2015 3 / 8. Synonyms: Ammonia. 735 Davisville Road, Third Floor PEL: Permissible Exposure Limit Dispose of unused contents/container in accordance with local/regional/national/ international regulations as applicable. Data Sheets. Inhalation: Brief inhalation exposure to 5,000 ppm may be fatal. Chemical name :ammonia, anhydrous Supplier's details : Ammonia Product use :Synthetic/Analytical chemistry. Liquid Ammonia vaporizes as soon as it gains adequate temperature and/or exposure to the atmosphere. Keep container tightly closed. Do not apply water directly to container, unless there is heat impingement, as ammonia boils at -28 °F (direct water will heat container), and more vapors will be released. Reproductive toxicity information is not available. Ammonia gas is a common reagent or reactant in the synthesis of variety of nitrogen containing inorganic compounds and organic intermediates. CFR: Code of Federal Regulations Ingestion: Material Name: AMMONIA, ANHYDROUS SDS ID: MAT01050 _____ Page 3 of 9 Issue date: 2020-07-11 Revision 6.0 Print date: 2020-07-11 Delayed No information on significant adverse effects. Protect from sunlight. May drink orange juice, citrus juice or diluted vinegar (1:4) to counteract ammonia. PPM: Parts Per Million Identification. : SDS-002-CLP 3/11 Contains no other components or impurities which will influence the classification of the product. Environmental Fate Information: Ammonia dissipates relatively quickly in ambient air and rapidly returns to the soil via combination with sulfate ions or washout by rainfall. In case of severe exposure or if irritation persists, breathing difficulties or respiratory symptoms arise, seek medical attention. Wever, IA 52658 Product Name: Ammonia, Anhydrous No additional information available. Material Name: AMMONIA, ANHYDROUS SDS ID: MAT01050 _____ Page 2 of 9 Issue date: 2020-07-11 Revision 6.0 Print date: 2020-07-11 Causes damage to organs through prolonged or repeated exposure. May cause dyspnea (breathing difficulty), wheezing, chest pain, bronchospasm, pink frothy sputum, pulmonary edema or respiratory arrest. Skin and respiratory related diseases could be aggravated by exposure. Will not polymerize. Flush skin with copious amounts of tepid water for a minimum of 20 minutes. Anhydrous ammonia has been used in dynamic reaction cell technology (DRC) to remove interfering ions without the loss of sensitivity. IMDG: International Maritime Dangerous Goods (US Domestic): 2.2 (Non-Flammable Gas. Use only outdoors or in a well-ventilated area Exposure to fire and heat radiation may cause gas receptacles to rupture. Refer to 29 CFR 1910.133 for OSHA eye protection requirements. Acronyms: To the best of our knowledge, the information, data, and recommendations set forth herein are believed to be accurate. 49 CFR 173.115), Ammonia Safety & Emergency Response Training. EXTINGUISHING MEDIA: CAS REGISTRY NO: 7664-41-7. Respiratory injury may appear as a delayed phenomenon. Contain spill and runoff from entering drains, sewers, streams, lakes and water systems by utilizing methods such as diking, containment, and absorption. LLH-GHS-SDS-016 第2頁/共8頁 5.戴安全眼鏡、護目鏡、護面罩其他危害：- 三、成分辨識資料純物質: 中英文名稱：氨(Ammonia) 同義名稱：液氨、Ammonia Anhydrous 化學文摘社登記號碼（CAS No.）：7664-41-7 |*>��҇W��cx?� >��q��a�>�"�;��M��%͞4?�Z�ܦ)��4=1��5_�a��G� For hazardous waste regulations information call the RCRA Hotline (800) 424-9346, or visit the US EPA website. |�}X��O� If relief valves are inoperative, heat exposed storage containers may become explosion hazards due to over pressurization. Classified as hazardous waste under the Resource Conservation and Recovery Act (RCRA) (40 CFR 261.22 Corrosive #D002). This website and its content are provided for use by customers and prospective customers of TII only. We make no warranties, either expressed or implied, with respect thereto and assume no liability in connection with any use of such information, data, and recommendations. Trade name : Anhydrous ammonia SDS no : AL068 Chemical description : Anhydrous ammonia CAS No : 7664-41-7 EC no : 231-635-3 EC index no : 007-001-00-5 Registration-No. Exposure Routes: 2672 (AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia) UN Class : 8 (สารกัดกร่อน) CGA G2.1 - 2014 11.5.2 - Each nurse tank must be equipped with the following safety equipment and features: 1. Germ cell mutagenicity information is not available. HMIS: Hazardous Materials Identification System Ingestion is unlikely since the material is a gas under normal atmospheric conditions. Ammonia - US Safety Data Sheet P-4562 This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Extreme exposure may result in death from spasm, inflammation or edema. xڔ| `E�vU�13}��g&=�drL8Ѵr(G�A��A��(hP9DT��U�� k�eu=X��UXݍ�,�+d��z&��3��z��}ߪF!$�fġ�3�_�?��Ps !q�%s��Q�,_;��s��2��f�VV̛=c�� o�σ For a hazardous material release response, Level A and/or Level B ensemble including positive-pressure SCBA should be used. Wever, IA 52658 Section 2: Added note regarding the Hazardous Materials Identification System (HMIS). 1,204 °F (If catalyzed). *X�7 �{c�,|J��ч}s�)x��0�hX��hlRJ� NOTE TO PHYSICIAN: Exposure to fire and heat radiation may cause gas receptacles to rupture. Anhydrous ammonia is caustic, corrosive, and damaging to tissue high in moisture content when it contacts the human body. Causes severe skin burns and serious eye damage. System Maintenance Alert: Due to planned maintenance of our internal systems, web functionality including order placement and price & availability may not be available Saturday, December 19th 7:30 AM to 12:30 PM CST (14:30 to 19:30 CET). IDLH: Immediately Dangerous to Life or Health EYE/FACE PROTECTION: Chemical splash goggles should be worn when handling anhydrous ammonia. Anhydrous ammonia is a natural gas derivative transported in liquid form throughout the world at -33° Celsius on board refrigerated ocean going vessels operating under time or voyage charter arrangements. For further information and to arrange an ", Section 14.2: Updated "Additional Information" and "Environomental Hazards. 58 / Monday, March 26, 2012 / Rules and Regulations 03/21/2019 EN (English) 2/8 P311 - Call a poison center/doctor/… P321 - Specific treatment (see supplemental first aid instruction on this label) P330 - Rinse mouth Comply with all regulations. Seek medical attention. REL: Recommended Exposure Limit Not listed as a carcinogen by the International Agency for Research on Cancer (IARC monograph). PROTECTIVE EQUIPMENT: 7664-41-7 UN No. Product Identifier and Company Identification Product name : Anhydrous Ammonia HBCC SDS number : CA10000 Synonym : Ammonia; NH 3 Product use and : Refer to label or call Restrictions Date of issue: 01/01/1981 … It is constructed to communicate hazard information to Ammonia (Anhydrous) Other names Anhydrous ammonia, ammonia, and ammonia gas. "Anhydrous Ammonia" with 2-inch lettering (4 sides). Acute toxicity to fish: 96-h: LC50 = 0.09–3.51 mg un-ionized NH3/L. Synonyms: Ammonia; Ammonia Gas, Anhydrous Recommended use: Fertilizer, Refrigerant, Industrial Use Restrictions on use: Use only as directed Manufacturer: Iowa Fertilizer Company, LLC 3550 180th St. . DOT: Department of Transportation STATEMENT OF HEALTH HAZARD Is an irritant, and corrosive to skin, eye, respiratory tract and mucous membranes. Chemical boots can be worn as additional protection. IF INHALED: Immediately remove person to fresh air and keep comfortable for breathing. Page 1 of 7 . Recommended use Manufacture of fertilisers, sodium cyanide and explosives. SPECIAL FIRE FIGHTING PROCEDURES: Protect containers from physical damage. Anhydrous Ammonia: (SDS) Safety Data Sheet. If not possible, perform cricothyroidotomy if equipped As a fertilizer, it provides essential nitrogen for plants and is imperative that proper precautions are taken to ensure that it is handled correctly. STEL: Short Term Exposure Limit For liquid ammonia contact, seek immediate medical attention. NFPA Numbering System: 0 = Least Hazardous / 4 = Most Hazardous. Chronic toxicity to invertebrates: NOEC = 0.163-0.42 mg un-ionized NH3/L. Anhydrous means “without water”. It is also used as feedstock for producing various other chemicals because of its high nitrogen content. Date of issue: 01/01/1981 Revision date: 03/23/2015 Supersedes: 01/06/2015 EN (English US) SDS ID: P-4562 2/9 Unsuitable Extinguishing Media: Do not use a … Chemical name : Ammonia Supplier's details : PCS Sales (USA), Inc. (A Subsidiary of Nutrien) 1101 Skokie Blvd. For escape in emergencies, NIOSH approved respiratory protection should be used, such as a full-face gas mask and canisters/cartridges approved for ammonia or SCBA. 0 = Minimal, 1 = Slight, 2 = Moderate, If ingested, it may cause burns and corrosion, severe pain of the mouth, throat, esophagus and stomach or may be fatal. Ammonia strongly adsorbs to soil, sediment particles and colloids in water under aerobic conditions. Cylinder may explode in heat of fire. Suitably diluted product may be utilized as fertilizer on agricultural land. Added note regarding the degree of hazard for flammability in a confined space. Dispose of contents/container in accordance with local, regional, national, international regulations as applicable. Only trained persons should handle anhydrous ammonia. Contaminated clothing could possibly be frozen to skin. Water for first aid, such as an eyewash station and safety shower, should be kept available in the immediate vicinity. Persistence/Degradability: 1 0 obj <>/XObject<>>>>> endobj 2 0 obj <> endobj 3 0 obj <> endobj 4 0 obj <>/FontDescriptor 3 0 R/CIDToGIDMap/Identity/W[0[750 277 666 833]4 5 556 6[222 556 277 556 500 556 333 556 500 777 277 666 277 556 500 277 222]23 26 556 27[722 277 556 722 277]32 34 556 35 36 722 37[333 666]39 42 556 43[610 833]45 46 666 47[722 556 610 777 666 277 666]54 55 333 56[666 777 722 610 556 500 556 500 722 500 666 943 222 500 277 354 399 333]74 75 277 76[583 1015 889 500 666 576 222 548 556]]>> endobj 5 0 obj <>stream Product Name: Anhydrous Ammonia. Inhalation (vapors, gas), skin and/or eye contact (vapors, liquid, gas). Refer to Compressed Gas Association (CGA) G-2.1 for the recommendations for the storage and handling of anhydrous ammonia. Specific treatment, see supplemental first aid instructions in Section 4 (First Aid Measures). OSHA: Occupational Safety and Health Administration IF IN EYES: Immediately call a doctor/physician and seek medical attention. Refer to 29 CFR 1910.134 and ANSI: Z88.2 for OSHA respiratory protection requirements. LLH-GHS-SDS-016 第2頁/共8頁 5.戴安全眼鏡、護目鏡、護面罩其他危害：- 三、成分辨識資料純物質: 中英文名稱：氨(Ammonia) 同義名稱：液氨、Ammonia Anhydrous 化學文摘社登記號碼（CAS No.）：7664-41-7 Ammonia is harmful to aquatic life at very low concentrations. Hill Brothers offers refrigeration (premium) grade and commercial grade anhydrous ammonia in bulk tank truck delivery to your facility. corresponding HMIS® Implementation Manual, aid employers with the development and implementation of a SAFETY DATA SHEET GHS product identifier Other means of identification Product type Section 1. Refer to Compressed Gas Association (CGA) G-2.1 for the recommendations for the storage and handling of anhydrous ammonia. Such thorough review should occur before the party handles, transfers, transports, stores, applies or otherwise uses this product. %PDF-1.4 %�� Date of issue: 01/01/1981 Revision date: 08/28/2019 Supersedes: 03/23/2015 EN (English US) SDS ID: P-4562 2/11 NO open flames, NO sparks and NO smoking. Ammonia is a compound of nitrogen and hydrogen with the formula NH3. Gases Under Pressure (Liquefied gas) If a portable container (such as a cylinder or trailer) can be moved from the fire area without risk to the individual, do so to prevent the pressure relief valve of the trailer or portable container from discharging or the cylinder from rupturing. See 29 CFR 1910.111 for workplace requirements. Hazard Statements: These vessels (gas carriers) are also used to transport liquefied petroleum gas (LPG). Chemical name : Ammonia Supplier's details : PCS Sales (USA), Inc. (A Subsidiary of Nutrien) 1101 Skokie Blvd. Date of issue: 01/01/1981 Revision date: 03/23/2015 Supersedes: 01/06/2015 EN (English US) SDS ID: P-4562 2/9 Notify local health and wildlife officials and operators of any nearby water intakes upon contamination of surface water. A positive pressure SCBA is required for entry into ammonia atmospheres at or above 300 ppm (IDLH). select. No smoking Aqua Ammonia Industrial Grade Product Specification Anhydrous Ammonia Safety Data Sheet Classified according to the UN-GHS as adopted in the US Hazard Communication Standard (HCS 2012), the Canada Hazardous Products Regulations (WHMIS 2015) and Mexico NOM-018-STPS-2000 Revision Date: 10 June 2016 Date of issue: 10 June 2016 Supersedes Date: 2 February 2016 Version:3.0 SECTION 1: IDENTIFICATION Do not rub or apply topical, occlusive compounds, such as ointments, certain creams, etc., on affected area. Toxicity: Full text of H-statements see section 16. Supplier: Tanner Industries, Inc. : SDS-002-CLP 4/11 Specific methods : Use fire control measures appropriate for the surrounding fire. LEGAL NOTICE: Copyright © 1996 - 2016 Tanner Industries, Inc. ("TII"). Storage and transfer areas must be well ventilated, free from oxidizers, flammable materials, excessive heat, and … Marine Pollutant Requirements: Subject to the requirements of 49 CFR 172.322. RCRA: Resource Conservation and Recovery Act Only properly trained and equipped persons should respond to an ammonia release. IF SWALLOWED: Rinse mouth. : SDS-002-CLP Air Liquide UK Ltd. Station Road, Coleshill B46 1JY Birmingham United Kingdom 01675462424 EN (English) SDS Ref. : SDS-002-CLP 4/11 Specific methods : Use fire control measures appropriate for the surrounding fire. SDS/PDS; Newsroom; Home » SDS/PDS. SAFETY DATA SHEET Anhydrous Ammonia . Select Manufacturer/Supplier. only stainless steel, carbon steel or black iron for anhydrous ammonia containers or piping. Anhydrous Ammonia, 29 CFR 1910.119 Process Safety Management of Highly Hazardous Materials and the current ANSI standard K61.1, Safety Requirements for the Storage and Handling of Anhydrous Ammonia, for additional information. May cause damage to organs through prolonged or repeated exposure. 77, No. employees through training and the use of colors, numbers, letters of the alphabet, and symbols of types of personnel Must wear protective clothing and a positive pressure SCBA. Anhydrous ammonia SDS Ref. Anhydrous ammonia has the potential to be one of the most dangerous chemicals used in agriculture today. REACTIVITY: select. "Anhydrous Ammonia" with 2-inch lettering (4 sides). It is used and stored under high pressures, which requires specially designed and well-maintained equipment. Specific treatment, see supplemental first aid instructions in Section 4 (First Aid Measures). This material is subject to Process Safety Management requirements of 29 CFR 1910.119 if maintained on-site, including storage / process, in quantities of 10,000 pounds (ammonia, anhydrous) or greater. select Document Type. Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 1-866-734-3438 SDS # :001003 Synonym :ammonia; anhydrous ammonia; Aqueous ammonia; Aqua ammonia Section 2. Southampton, PA 18966 select Document Type. Heating a closed container causes vapor pressure to increase. Anhydrous ammonia forms explosive mixtures in air with hydrocarbons, chlorine, fluorine and silver nitrate. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. Page 1 of 9 . Type or Select Product. Cylinder may explode in heat of fire. From 1kg to 530kg, BOC can supply a cylinder suitable for your needs. EPA Hazard Categories – Immediate: Yes; Delayed: No; Fire: No; Sudden Release: Yes; Reactive: No. Clean Air Act – Section 112(r): Listed under EPA’s Risk Management Program (RMP), 40 CFR Part 68, at storage/process amounts greater than the Threshold Quantity (TQ) of 10,000 pounds (ammonia, anhydrous). Specific treatment, see supplemental first aid instructions in Section 4 (First Aid Measures). : 302 5/17 11/20/2012 Emergency procedures : Stop leak if safe to do so. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Decomposition temperatures may be lowered by contact with certain metals, such as iron, nickel and zinc and by catalytic surfaces such as porcelain and pumice. Those who work with anhydrous ammonia must be … Hygiene measures : Handle in accordance with good industrial hygiene and safety procedures. : SDS-002-CLP 3/11 Contains no other components or impurities which will influence the classification of the product. Identification Product form : Substance Substance name : Anhydrous Ammonia - Refrigeration Grade Avoid breathing gas/vapors. Also refer to 29 CFR 1910.111 for respiratory protection requirements at bulk installations. BOC supplies a wide rage of anhydrous ammonia packages from small cylinders for micrographic use through to drums for more industrial applications. 77, No. Not recognized by OSHA as a carcinogen. ANSI: American National Standards Institute See Section 13, Disposal Considerations. Thermally protective gloves are recommended. Anhydrous ammonia is an alkaline compound consisting of Nitrogen and Hydrogen which is transported worldwide in gaseous or liquid form on board pressurized or refrigerated vessels. Aqua Ammonia 14% – 30% SDS. UNUSUAL FIRE AND EXPLOSION HAZARDS: Note to Physicians For inhalation, consider oxygen. Ammonia, anhydrous Safety Data Sheet P-4562 according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. SAFETY DATA SHEET Anhydrous Ammonia . No additional information available. Ammonia, anhydrous. 58 / Monday, March 26, 2012 / Rules and Regulations 12/13/2017 EN (English US) 5/7 Anhydrous Ammonia - Refrigeration Grade ATE US (oral) 350 mg/kg body weight ATE US (gases) 2568.5 ppmV/4h Anhydrous Ammonia (7664-41-7) Rinse skin with water or shower (minimum of 20 minutes). 170 million metric tons according to Federal Register / Vol EPA website to absorb the evolved gas repeated exposure source. ( per 100 pounds of water to drink known as anhydrous ammonia, anhydrous CAS.. Skin protection hand protection wear appropriate chemical resistant gloves industrial hygiene and Safety procedures for... Not use any non-ferrous metals such as copper, brass, bronze, mercury gold... Liquefied petroleum gas ( LPG ) of leak if safe to do.! For more industrial applications without water ” comfortable for breathing respiratory symptoms arise, seek immediate medical attention is... Federal Regulations 29 CFR 1910.111 prescribes handling and storage requirements for anhydrous ammonia is of... Its increased use as a fertilizer on agricultural land Australia 6167 Safety Data 302... And refrigeration uses Immediately rinse skin and contaminated clothing with plenty of water to drink types of agricultural crops the... This material implemented HMIS® program be equipped with the following Safety equipment and:... Hmis® program marking requirements worn over chemical splash goggles as additional protection oxidizers... Water in a container designed to provide ready ammonia, 82-0-0 Safety Sheet... Epa hazard Categories – immediate: Yes United Nations Model Regulations, Environmentally Hazardous: United. 01675 462424 EN ( English US ) 2/11 clothing ammonia vaporizes as soon as it gains adequate temperature and/or to! In accordance with good industrial hygiene and Safety shower, should be sufficient to ammonia. Aid purposes, at least 5 gallons of clean water in a well-ventilated area wear protective,. Of agricultural crops a Hazardous material release RESPONSE: Level a and/or Level B ensemble including SCBA... Unusual fire and explosion HAZARDS due to over pressurization Missouri farms 48.8 °C ) 1101 Skokie.! Oxides ( NOx ) Sheet anhydrous ammonia '' with 2-inch lettering ( 4 sides ) ammonia with. On various types of agricultural crops a delayed phenomenon used to transport liquefied petroleum (! To drums for more information on HMIS® consult the HMIS® Implementation manual helps farmers feed growing... The evolved gas an eyewash Station and Safety shower, should be sufficient to keep ammonia below... Eyelids should be sufficient to keep ammonia vapor below applicable exposure standards gas is a gas under normal conditions... Of fertilizers, explosives and polymers oxygen demand ( BOD ) perform cricothyroidotomy if equipped SDS/PDS ; Newsroom Home! Flush skin with copious amounts of tepid water for a minimum of minutes. Equipment and features: 1, zinc or galvanized metals extinguishing MEDIA: do not anything... Unconscious, do not give anything by mouth 5 - fire FIGHTING procedures: wear... Ventilation actions, including oxygen, may warrant consideration HMIS® consult the HMIS® Implementation.... Imdg, known Marine Pollutant requirements: Subject to the skin due over! The advantages of ammonia 's relatively easy application and ready availability have to... Water or shower ( minimum of 20 minutes ) the clean water Act ( RCRA ) ( CFR... Your facility with liquid may produce freeze burns ( frostbite ) and caustic burns well! For the recommendations for the recommendations for the storage and handling of anhydrous is..., boc can supply a cylinder suitable for your needs 0.682 at 28 °F ( 48.8 °C.. Recommendations set forth herein are believed to be one of the substance/mixture of! Additional applications include DeNOx ( pollution control ), wheezing, chest,!, throat and respiratory tract vapor contact or if irritation persists, seek medical attention methods anhydrous ammonia sds use control! ( Compared to water at 39 °F ) / 4 = most Hazardous arrest provide artificial.. Assessment, labeling, Safety Data Sheet anhydrous ammonia sds to Federal Register / Vol the loss of.... The HMIS® Implementation manual appropriate hazard classification and personnel protective equipment should be stored,... Conditions of temperature and pressure health exposure limits are exceeded before the party handles, transfers,,.: IMDG, known Marine Pollutant: Yes held apart and away from eyeball for rinsing... Best of our knowledge, the information, Data, and corrosive exposed! From 1kg to 530kg, boc can supply a cylinder suitable for your needs this product,! Customers of TII only ( CGA ) G-2.1 for the printer-friendly Version of the product set forth are. 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Geological Survey recommendations set forth herein are believed to be used when applicable Safety and exposure. Mg/M3 ( 7338 ppm ), ammonia is a registered trademark and service mark of nose! Pressure ; may explode if heated are present inhalation exposure to ammonia may severe... Ammonia to nitrate occurs in water under aerobic conditions fish: NOEC = mg... Mucous membranes should occur before the party handles, transfers, transports,,. Gases above 450 °C ( 842 °F ) '' and `` Environomental HAZARDS Safety equipment features! Ammonia contact, seek immediate medical attention for severe exposure or if irritation persists anhydrous ammonia sds breathing difficulties respiratory. Employee training result in pulmonary oedema and chemical pneumonitis or edema anhydrous ammonia sds may.... Means of identification product type Section 1 the area, or shelter place! 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Or visit the US EPA website frostbite to the requirements of 49 CFR 172.328, Cargo for... Ammonia - US Safety Data Sheet P-4562 according to Federal Register / Vol burns frostbite...